Accession Number N20120017919
Title Compositional Effects on Nickel-Base Superalloy Single Crystal Microstructures.
Publication Date Oct 2012
Media Count 42p
Personal Author A. Garg M. V. Nathal R. A. MacKay R. B. Rogers T. P. Gabb
Abstract Fourteen nickel-base superalloy single crystals containing 0 to 5 wt% chromium (Cr), 0 to 11 wt% cobalt (Co), 6 to 12 wt% molybdenum (Mo), 0 to 4 wt% rhenium (Re), and fixed amounts of aluminum (Al) and tantalum (Ta) were examined to determine the effect of bulk composition on basic microstructural parameters, including gamma' solvus, gamma' volume fraction, volume fraction of topologically close-packed (TCP) phases, phase chemistries, and gamma - gamma'. lattice mismatch. Regression models were developed to describe the influence of bulk alloy composition on the microstructural parameters and were compared to predictions by a commercially available software tool that used computational thermodynamics. Co produced the largest change in gamma' solvus over the wide compositional range used in this study, and Mo produced the largest effect on the gamma lattice parameter and the gamma - gamma' lattice mismatch over its compositional range, although Re had a very potent influence on all microstructural parameters investigated. Changing the Cr, Co, Mo, and Re contents in the bulk alloy had a significant impact on their concentrations in the gamma matrix and, to a smaller extent, in the gamma' phase. The gamma phase chemistries exhibited strong temperature dependencies that were influenced by the gamma and gamma' volume fractions. A computational thermodynamic modeling tool significantly underpredicted gamma' solvus temperatures and grossly overpredicted the amount of TCP phase at 982 C. Furthermore, the predictions by the software tool for the gamma - gamma' lattice mismatch were typically of the wrong sign and magnitude, but predictions could be improved if TCP formation was suspended within the software program. However, the statistical regression models provided excellent estimations of the microstructural parameters based on bulk alloy composition, thereby demonstrating their usefulness.
Keywords Aluminum
Chromium
Cobalt
Concentration(Composition)
Heat resistant alloys
Lattice parameters
Mathematical models
Molybdenum
Nickel alloys
Rhenium
Single crystals
Tantalum
Thermodynamics


 
Source Agency National Aeronautics and Space Administration
NTIS Subject Category 71N - Nonferrous Metals & Alloys
Corporate Author National Aeronautics and Space Administration, Cleveland, OH. NASA John H. Glenn Research Center at Lewis Field.
Document Type Technical report
Title Note N/A
NTIS Issue Number 1316
Contract Number N/A

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